孙青
理学博士、讲师。主持江西省自然科学青年基金项目1项、江西省教育厅科学技术研究项目1项和博士科研启动基金1项,参与编撰教材一部,共发表SCI论文34篇,其中以第一作者或者通讯作者在 J. Am. Chem. Soc., Angew. Chem. Int. Ed., Green Chem., Org. Lett.,等国际知名期刊上发表论文14篇(IF > 10以上论文3篇)。
研究方向:均相和非均相催化反应机理的理论研究
电子邮件:sunqing@nchu.edu.cn
教育经历:
[1] 2014-09至2020-08,厦门大学,理论与计算化学专业,博士
[2] 2019-09至2020-09,美国加州大学戴维斯分校,国家公派联合培养博士生
[3] 2010-09至2014-06,河南农业大学,应用化学专业,学士
工作经历:
2020-10 至今, 南昌航空大学, 环境与化学工程学院, 讲师
讲授课程:
[1]《计算化学》
[2]《专业英语》
[3]《精细有机合成》
主持或参与的代表性科研项目:
[1] 江西省自然科学青年基金项目,基于单电子转移策略的廉价过渡金属催化自由基反应机理的理论研究(20224BAB213013),10万,主持。
[2] 江西省教育厅科学技术研究项目,过渡金属催化单电子转移型有机反应的理论研究(GJJ210906),2万,主持。
[3] 博士科研启动基金,多官能团炔烃有机反应机理的理论研究(EA202002385),20万,主持。
代表性论文:
[1] Long-Jin Zhong; Zhi-Qiang Xiong; Xuan-Hui Ouyang; Yang Li; Ren-Jie Song*; Qing Sun*; Xin Lu; and Jin-Heng Li*; Intermolecular 1,2-difunctionalization of alkenes enabled by fluoroamide-directed remote benzyl C(sp3)-H functionalization. J. Am. Chem. Soc., 2022, 144, 339-348.
[2] Bo-Han Zhu; Sheng-Bing Ye; Min-Ling Nie; Zhong-Yang Xie; Yi-Bo Wang; Peng-Cheng Qian*; Qing Sun*; Long-Wu Ye; and Long Li*; I2-catalyzed cycloisomerization of ynamides: chemoselective and divergent access to indole derivatives. Angew. Chem. Int. Ed., 2023, DOI: 66, e202215616.
[3] Chong-Yang Shi; Tao Han; Feng-Lin Hong; Long-Wu Ye*; Qing Sun*; Ming-Yu Teng*; Construction of spirolactams by unexpected oxidative cyclization of alkenyl diynes via copper catalysis. Org. Lett., 2023, 25, 1525-1529.
[4] Tong-De Tan; Tong-Yi Zhai; Bin-Yang Liu; Long Li; Peng-Cheng Qian*; Qing Sun*; Jin-Mei Zhou; Long-Wu Ye*; Controllable synthesis of benzoxazinones and 2-hydroxy-3-indolinones by visible-light-promoted 5-endo-dig N-radical cyclization cascade. Cell Reports Physical Science, 2021, 2, 100577.
[5] Yi-Miao He*; Li-Mei Tian#; Xue-Xue Chang#; Ze-Ming Qu; Yan-Min Huang; Chu-Sheng Huang; Qing Sun*; Hong-Gen Wang*; Rhodium-catalyzed formal [4 + 3] annulation reaction of N-methoxybenzamides with gem-difluorocyclopropenes: A combination of experimental and theoretical studies. Chin. Chem. Lett., 2022, 33, 2987-2992.
[6] Jia-Jie Chen; Jia-Yi Liu; Xi-Xi Cao; Jing-Xin Hu; Xin Lu; Wen-Bo Shen; Qing Sun*; Ren-Jie Song*; Jin-Heng Li*; Theoretical insights into the mechanism and origin of chemoselectivity in the catalyst- and directing group-dependent oxidative cyclization of diynes with pyridine N-oxides. Org. Chem. Front., 2022, 9, 5168-5177.
[7] Chong-Yang Shi#; Ji-Jia Zhou#; Pan Hong#; Bo-Han Zhu; Feng-Lin Hong; Peng-Cheng Qian; Qing Sun*; Xin Lu; Long-Wu Ye*; Efficient synthesis of tetracyclic γ-lactams via gold-catalyzed oxidative cyclization of alkenyl diynes. Org. Chem. Front., 2022, 9, 2557-2562.
[8] Li-Ping Chen; Jiang-Fei Chen; Yu-Jiao Zhang; Xing-Yi He; Ya-Fei Han; Yu-Ting Xiao; Gui-Fen Lv; Fan Teng*; Qing Sun*; Xin Lu; Jin-Heng Li*; Atroposelective carbonylation of aryl iodides with amides: facile synthesis of enantioenriched cyclic and acyclic amides. Org. Chem. Front., 2021, 8, 6067-6073.
[9] Liang Zeng; Jing-Hao Qin; Gui-Fen Lv; Ming Hu*; Qing Sun*; Xuan-Hui Ouyang*; De-Liang He*; Jin-Heng Li*; Electrophotocatalytic reductive 1,2-diarylation of alkenes with aryl halides and cyanoaromatics. Chin. J. Chem., 2023, 41, DOI:10.1002/cjoc.202300174.
[10] Shuang-Long Li; Ren Wang; Jia-Jie Chen; Hao Zhang; Gao-Kai Hou; Xin Lu; Qing Sun*; Yang Li*; Lewis acid catalyzed three-component carbofunctionalization of styrenes with diacyl peroxides and nucleophiles. Adv. Synth. Catal., 2023, 365, 17-22.
[11] Qing Sun#*; Tian-Yu Deng#; Jia-Jie Chen; Jia-Yi Liu; Xin Lu; Zhi-Xia Zhang; Jin-Heng Li*; Insights into the gold(I)-catalyzed intermolecular annulations of alkynes with N-allenamides: a mechanistic DFT study. Dalton Trans., 2022, 51, 3734-3739.
[12] Qing Sun; Xin Lu; Dean J. Tantillo*; Dynamic effects in intramolecular Schmidt reactions – entropy, electrostatic drag and selectivity prediction. ChemPhysChem, 2021, 22, 649-656.
[13] Qing Sun; Pan Hong; Dong-Dong Wei; An-An Wu*; Kai Tan; Xin Lu*; Chemoselectivity in gold(I)-catalyzed propargyl ester reactions: insights from DFT calculations. Front Chem., 2019, 7, 609.
[14] Cai-Ming Wang#; Lin-Jun Qi#; Qing Sun#; Bo Zhou; Zhi-Xin Zhang; Zai-Fa Shi; Shui-Chao Lin; Xin Lu*; Lei Gong; Long-Wu Ye*; Transition-metal-free oxidative cyclization of N-propargyl ynamides: stereospecific construction of linear polycyclic N-heterocycles. Green Chem., 2018, 20, 3271-3278.
[15] Yin Xu; Qing Sun; Tong-De Tan; Ming-Yang Yang; Peng Yuan; Shao-Qi Wu; Xin Lu*; Xin Hong; Long-Wu Ye*; Organocatalytic enantioselective conia-ene-type carbocyclization of ynamide cyclohexanones: regiodivergent synthesis of morphans and normorphans. Angew. Chem. Int. Ed., 2019, 58, 16252-16259.
[16] Wen-Bo Shen#; Xin-Yu Xiao#; Qing Sun; Bo Zhou; Xin-Qi Zhu; Juan-Zhu Yan; Xin Lu*; Long-Wu Ye*; Highly site selective formal [5+2] and [4+2] annulations of isoxazoles with heterosubstituted alkynes by platinum catalysis: rapid access to functionalized 1,3-oxazepines and 2,5-dihydropyridines. Angew. Chem. Int. Ed., 2017, 56, 605-609.
[17] Wen-Bo Shen; Qing Sun; Long Li; Xin Liu; Bo Zhou; Juan-Zhu Yan; Xin Lu*; Long-Wu Ye*; Divergent synthesis of N-Heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold. Nat. Commun., 2017, 8, 1748-1756.
[18] Chao Shu#; Chong-Yang Shi#; Qing Sun; Bo Zhou; Tian-You Li; Qiao He; Xin Lu*; Rai-Shung Liu; Long-Wu Ye*; Generation of endocyclic vinyl carbene complexes via gold-catalyzed oxidative cyclization of terminal diynes: towards naphthoquinones and carbazolequinones. ACS Catal., 2019, 9, 1019-1025.
[19] Ya-Qiang Xie; Qing Sun; Ya-Wen Fu; Lei Song; Jun Liang; Xun Xu; Hong-Tao Wang; Jian-Hui Li; Song Tu*; Xin Lu*; Jun Li*; Sponge-like quaternary ammonium-based poly(ionic liquid)s for high CO2 capture and efficient cycloaddition under mild conditions. J. Mater. Chem. A, 2017, 5, 25594-25600.
[20] Xin-Qi Zhu; Qing Sun; Zhi-Xin Zhang; Bo Zhou; Pei-Xi Xie; Wen-Bo Shen; Xin Lu*; Jin-Mei Zhou; Long-Wu Ye*; Zinc-catalyzed reaction of isoxazoles with thioynol ethers involving an unprecedented 1,2-sulfur migration. Chem. Commun., 2018, 54, 7435-7438.
[21] Xin-Qi Zhu; Han Yuan; Qing Sun; Bo Zhou; Xiao-Qin Han; Zhi-Xin Zhang; Xin Lu*; Long-Wu Ye*; Benign catalysis with zinc: atom-economical and divergent synthesis of nitrogen heterocycles by formal [3+2] annulation of isoxazoles with ynol ethers. Green Chem., 2018, 20, 4287-4291.
[22] Xiao-Jie Liu#; Sheng-Yun Zhou#; Yu-Ting Xiao; Qing Sun; Xin Lu; Yang Li*; Jin-Heng Li*; Photocatalytic decarboxylative [3+2] and [4+2] annulation of enynals and γ,σ-unsaturated N-(acyloxy)phthalimides by NaI/PPh3 catalysis. Org. Lett., 2021, 23, 7839-7844.
[23] Hui‐Min Jiang; Qing Sun; Jin‐Peng Jiang; Jing‐Hao Qin*; Xuan‐Hui Ouyang*; Ren‐Jie Song*; Copper-catalyzed oxidative 1,2-alkylarylation of styrenes with unactivated C(sp3)-H alkanes and electron-rich aromatics via C(sp3)-H/C(sp2)-H functionalization. Adv. Synth. Catal., 2022, 364, 2772-2782.
[24] Hui-Min Jiang; Yi-Lin Zhao; Qing Sun; Xuan-Hui Ouyang*; Jin-Heng Li*; Recent advances in N-O Bond cleavage of oximes and hydroxylamines to construct N-heterocycle. Molecules, 2023, 28, 1775.
[25] Hui-Min Jiang; Jing-Hao Qin; Qing Sun; Dong Zhang; Jin-Peng Jiang; Xuan-Hui Ouyang*; Ren-Jie Song*; Jin-Heng Li*; Copper-promoted cross-coupling of nitroarenes with 4-alkyl-1,4-dihydropyridines using a peroxide-driven radical reductive strategy. Org. Chem. Front., 2022, 9, 4070-4077.
[26] Bo-Han Zhu; Wen-Ting Guo; Qing Sun; Peng-Cheng Qian*; Long-Wu Ye; Long Li*; Auxiliary-free remote dearomatizative nitrenoid transfer for enantioselective construction of spirolactams. Adv. Synth. Catal., 2021, 364, 314-318.
[27] Qi Xue; Qing Sun; Ting-Ting Zhang; Yang Li*; Jin-Heng Li*; Electrochemical oxygenation of sulfides with molecular oxygen or water: switchable preparation of sulfoxides and sulfones. Org. Biomol. Chem., 2021, 19, 10314-10318.
[28] Ya-Wen Yu; De-Zhi Chen*; Sha-Sha Xie; Qing Sun; Zhi-Xia Zhang; Gui-Sheng Zeng; Adsorption behavior of carbamazepine on Zn-MOFs derived nanoporous carbons: Defect enhancement, role of N doping and adsorption mechanism. Journal of Environmental Chemical Engineering, 2022, 10, 107660.
[29] Long-Shuai Zhang#; Xun-Heng Jiang#; Zi-Ai Zhong; Lei Tian; Qing Sun; Yi-Tao Cui; Xin Lu; Jian-Ping Zou*; Sheng-Lian Luo; Carbon nitride supported high-loading Fe single-atom catalyst for activation of peroxymonosulfate to generate 1O2 with 100 % Selectivity. Angew. Chem. Int. Ed., 2021, 60, 21751-21755.
[30] Zhi-Jia Huang; Jin-Hao Qin; Miao-Lian Huang; Qing Sun; Hai-Yang Xie; Yang Li*; Jin-Heng Li; Electrochemical dehydrogenative cyclization/aromatization of aniline-tethered alkylidenecyclopropanes: facile access to benzo[c] carbazoles. Org. Chem. Front., 2023, 10, 1557-1563.
[31] A. J. Youman; S. N. Rokey; J. P. Grabowski; Wen-Tao Guo; Qing Sun; S. Angles; J. R. Goodell; D. J. Tantillo; T. A. Mitchell; Experimental and theoretical investigation of the synchronicity of ambident silyloxypyrone-based (5+2) cycloadditions. J. Org. Chem., 2023, 88, 5972-5981.
[32] Yi Mu#; Ying Chen#; Qian Fu; Peng-Yuan He; Qing Sun; Jian-Ping Zou*; Li-Zhi Zhang; Deng-Ke Wang; Sheng-Lian Luo; Transformation of atrazine to hydroxyatrazine with alkali-H2O2 treatment: an efficient dechlorination strategy under alkaline conditions. ACS ES&T Water, 2021, 1, 1868-1877.
[33] Long-Fei Wang; Zhe-Yuan Fan; Xi-Xi Cao; Pan-Feng Fan*; Yu Xie*; Qing Sun; Jin-Sheng Zhao*; Template-free synthesis of g-C3N4 nanoball/biocl nanotube heterojunction with enhanced photocatalytic activity. Nanomaterials, 2022, 12, 2569.
[34] Zhen Yu; Yu-Ting Xiao*; Shi-En Guo*; Feng Min; Qing Sun; Ren-Jie Song*; Jin-Heng Li; Visible-light-driven selective reduction of CO2 by acetylene-bridged cobalt porphyrin conjugated polymers. ChemSusChem, 2022, 15, e202200424.